Redox: soil pH's energetic dance partner. When pH changes, pE must also change in response. The reverse is true also. In soil, that response departs from simple mirroring. So much so that it can seem to be two separate dances. Soil pH and pE have different causes of change and different effective buffering agents. The term 'buffering' is replaced in a pE context - it is called poise. A stabilized soil pE system is referred to as a well poised system, differences in soil buffering versus soil poise account for the departure from 1:1 mirroring. Now for the exciting stuff. To many of us, what makes soil different than geologic material is that it is in an excited state, excited mostly by solar energy as facilitated by living processes. Unlike soil pH, soil pE is directly influenced by these energy fluxes.